编号：CDUT-2023-48

标题：Application of 3D magnetic nanocomposites: MXene-supported Fe3O4@CS nanospheres for highly efficient adsorption and separation of dyes

入藏号：WOS:000766799600018

中国科学院文献情报中心期刊分区：环境科学与生态学1区/TOP（2022）

本校作者：许杰; 曾广勇*; 林清泉; 古懿

来源出版物：SCIENCE OF THE TOTAL ENVIRONMENT  卷: 822  文献号: 153544

出版年：2022

第一地址： 成都理工大学

关键词：MXene@Fe3O4@CS；Ultrasonic self-assembly；Adsorption capacity；Dyes removal

备注：本文已入围2023年9月ESI高被引论文（TOP Papers）

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摘要：Due to the presence of several hydroxyl and amino groups on the surface, chitosan (CS) has been reported to be a potential candidate to solve the pollution caused by dyes in different industrial wastewater. However, it is associated with the recycling issues. Nano-Fe3O4 has the advantages of easy magnetic separation and surface functionalization, which can improve the efficiency as well as selectivity of separation. However, its tendency for agglomeration can reduce the adsorption capacity. MXene can provide suitable support for both CS and Fe3O4 to construct new MXene@Fe3O4@CS composites. In this study, MXene@Fe3O4@CS magnetic nanosphere was synthesized by ultrasonic self-assembly to remove Congo red (CR). Scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and Fourier Transform Infrared (FT-IR) spectroscopy were employed to characterize the nanocomposites. According to the batch experiments, the adsorption kinetics were found to predominantly follow quasi-secondary rate kinetics. The adsorption followed Langmuir isotherm model. The adsorption process was found to be endothermic, entropy-driven, and thermodynamically spontaneous process. The adsorption capacity for CR was estimated as 620.22 mg/g.

文章链接地址:https://linkinghub.elsevier.com/retrieve/pii/S0048969722006362